Chemistry: electrical and wave energy – Processes and products
Patent
1990-04-16
1991-05-07
Niebling, John F.
Chemistry: electrical and wave energy
Processes and products
204 64T, 204244, 204245, C25C 300, C25C 326, C25C 700
Patent
active
050134132
ABSTRACT:
The invention relates to an apparatus for the continuous production of a polyvalent metal by electrolysis of a halide of the metal in a bath of at least one melted salt. The apparatus comprises an electrodismutation cell and a prereduction cell in a contiguous configuration sharing a common wall in the form of a grid which is electrically insulated from the cell walls. The electrodismutation cell includes at least one deposition cathode and at least two anodes which are connected to an at least partly direct current. The prereduction cell includes at least one anode and a cathode constituted by the grid, the anode and cathode being separated by a diaphragm and connected to an at least partly direct current power supply. Means are provided to cause bath flow by forced convection through the grid to produce a top-to-bottom movement in the electrodismutation cell and a bottom-to-top movement in the prereduction cell. Current densities are selected such that free metal is deposited in the electrodismutation cell without generation of halogen, while halogen is generated in the prereduction cell without production of free metal.
REFERENCES:
patent: 4338177 (1982-07-01), Withers et al.
patent: 4521281 (1985-06-01), Kodija
Lamaze Airy-Pierre
Paillere Patrick
Compagnie Europeenne du Zirconium Cezus of Tour Manhattan
Gorgos Kathryn
Niebling John F.
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