Apparatus for reducing carbon monoxide concentration, apparatus

Gas: heating and illuminating – Methane -containing product – or treatment or recovery process – Process including chemical reaction

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422177, 422196, 429 17, 429 19, 423246, C10L 300, C10B 3118, B01D 5000, H01M 824

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active

058431950

ABSTRACT:
A fuel reformer (30) includes a reformer unit (32) for receiving supplies of methanol and water and producing a hydrogen-rich reformed gas and a partial oxidizing unit (34) filled with a platinum-ruthenium alloy catalyst for oxidizing carbon monoxide in the reformed gas produced by the reformer unit (32) preferentially over hydrogen in the reformed gas. The platinum-ruthenium alloy catalyst charged in the partial oxidizing unit (34) lowers the concentration of carbon monoxide in the hydrogen-rich gas containing a trace amount of methanol to several ppm in its active temperature range of 80.degree. C. to 100.degree. C. This structure enables a gaseous fuel having extremely low concentrations of methanol and carbon monoxide to be produced by the fuel reformer (30) and supplied to polymer electrolyte fuel cells having an extremely low allowable limit of carbon monoxide concentration.

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Journal of Catalysis, vol. 142, pp. 254-262, 1993, Se H. Oh, et al., "Carbon Monoxide Removal from Hydrogen-Rich Fuel Cell Feedstreams by Selective Catalytic Oxidation".
IECEC, vol. 1, pp. 1.1203-1.1208, Aug. 8, 1993, Mahlon S. Wilson, et al., "Electrocatalysis Issues in Polymer Electrolyte Fuel Cells".
Patent Abstracts of Japan, vol. 95, No. 12, JP-A-07-315825, Dec. 5, 1995 & Chemical Abstracts, vol. 124, No. 16, Apr. 15, 1996, AN-207257, T. Fujimoto, "Oxidation of Co To Co2 and Manufacture of Hydrogen-Containing Gases for Fuel Cells".

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