Apparatus for producing stereo-regular polymers

Radiant energy – Photocells; circuits and apparatus – Optical or pre-photocell system

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20415922, 204155, 204165, 204168, 204170, 204DIG11, 250527, 250528, B01K 100

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active

042245257

ABSTRACT:
Stereo-regular polymers are produced by forming a moving stream of gaseous monomer having an electric dipole moment, irradiating the monomer with monochromatic light of a wavelength suitable for activating it, and orientating the activated monomer in an electric field. The activated, oriented monomer then polymerizes to form a stereo-regular polymer.
Alternatively, a monomer of the general formula ##STR1## can be used, where at least one of the R groups, the resonating R group, forms an electric dipole moment with the remainder of the monomer. The monomer is then irradiated with a monochromatic light beam having a frequency which resonates with a harmonic frequency resulting from the bond between the resonating R group and the remainder of the monomer. Activation of that particular bond on that particular type of monomer results in a stereo-regular polymer.
For best results, however, the two methods are combined.

REFERENCES:
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patent: 3405045 (1968-10-01), Hoskins
patent: 3421930 (1969-01-01), Knox et al.
patent: 3431137 (1969-03-01), Fadner
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patent: 3477932 (1969-11-01), Parts et al.
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patent: 4012301 (1977-03-01), Rich et al.
Vlasov et al., "Radiation polmerization from the gas phase . . ." Chem. Abs. 70:88309m 1969.
Bukin et al., "Photopolymerization by laser beam irradiation" Chem. Abs. 67:117483j 1967.

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