Coating apparatus – Gas or vapor deposition – With treating means
Reexamination Certificate
2001-06-11
2002-06-04
Mills, Gregory (Department: 1763)
Coating apparatus
Gas or vapor deposition
With treating means
C118S7230AN, C118S719000
Reexamination Certificate
active
06397776
ABSTRACT:
BACKGROUND OF INVENTION
This invention relates to plasma enhanced chemical vapor deposition. More particularly, it relates to deposition in an expanding thermal plasma (hereinafter referred to as “ETP”) system to coat large areas of a substrate.
The use of ETP to deposit coatings, especially protective coatings, on substrates is known. For example, U.S. Pat. No. 6,110,544 describes a method of forming coatings on a plastic substrate such as polycarbonate. The coatings that may be deposited include silicon oxide-based hardcoats, which can protect the plastic surface from abrasion. Also capable of deposition are metal oxide-based coatings such as zinc oxide. Coatings of these types are produced by introducing an organosilicon or organometallic compound into an ETP and causing the plasma stream produced by said ETP to impinge upon the surface of the substrate. By using ETP, particularly those using equilibrium thermal plasma arc generators, high coating deposition rates may be achieved at relatively low temperatures. It is particularly desirable that the substrate temperature be maintained lower than its glass transition temperature and/or softening temperature.
A problem with ETP deposition as described in the prior art is its incapability of efficiently producing a coating over a large area of a substrate. A single ETP source typically coats an area of about 75-200 cm
2
. Thus, many passes of a substrate into contact with the ETP would be necessary to coat the entire surface thereof.
Various publications disclose coating apparatus and systems using a plurality of coating units. For example, U.S. Pat. No. 4,948,485 discloses the disposition of a number of cascade arc plasma torches in a circular array around an axis, which may, for example, be a wire to be coated. Such a system is incapable being used to coat a single surface of, for example, a planar substrate.
U.S. Pat. Nos. 5,302,271 and 5,441,624 disclose multi-anodic arc coating systems in which the arcs are directed at a single surface of a substrate. Anodic arcs are fundamentally different from ETP sources in that they do not generate a thermal plasma and they use a consumable anode as the source material for deposition. In addition, those arcs are used for physical vapor deposition. As such, their operating parameters, such as arc-to-arc spacing, arc to substrate distance, and deposition pressure, are not adapted to ETP deposition.
It is of interest, therefore, to develop an apparatus and method suitable for coating relatively large areas of a substrate by ETP deposition. In particular, an apparatus and method that is adaptable to various configurations of substrates and to the particular parameters of ETP systems is desirable.
SUMMARY OF INVENTION
The present invention provides an ETP coating apparatus and process particularly adapted to efficiently coat large substrates. The invention can be configured so as to provide coatings having desirable properties, including uniformity and reproducibility.
One aspect of the invention is to provide a substrate coating apparatus. The apparatus comprises: a deposition chamber adapted to be maintained at subatmospheric pressure; support means in the deposition chamber for a substrate, the substrate having at least one surface; and a set of expanding thermal plasma generating means associated with the deposition chamber, the generating means being adapted to deposit a coating on the substrate. The set comprises at least two expanding plasma generating means, with all of the means in the set being codirectionally oriented.
Another aspect of the invention is to provide a method for coating a substrate. The method comprises generating a set of at least two expanding thermal plasma plumes to deposit a coating on said substrate, wherein each of the plumes in the set is codirectionally oriented.
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patent: 5474611 (1995-12-01), Murayama et al.
patent: 6110544 (2000-08-01), Yang et al.
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Browall Kenneth Walter
Gasworth Steven Marc
Iacovangelo Charles Dominic
Johnson James Neil
Morrison William Arthur
Alejandro Luz
General Electric Company
Johnson Noreen C.
Mills Gregory
Santandrea Robert P.
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