Apparatus for catalytically reducing dioxygen using dirhodium co

Details Apparatus for catalytically reducing dioxygen using dirhodium co Apparatus for catalytically reducing dioxygen using dirhodium co

1990-02-20

1991-09-10

Niebling, John F.

Chemistry: electrical and wave energy

Apparatus

Electrolytic

204291, C25B 1108

Patent

active

050471325

ABSTRACT:
Dirhodium complexes such as tetrakis (.mu.-2-anilinopyridinato)dirhodium are used in the catalytic reduction of dioxygen. An electric potential is applied to the dirhodium complex either dissolved in solution or supported by an electrode.

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S. E. Creager and R. W. Murray, "Electrochemical Reactivity of Manganese (II) Porphyrins, Effects of Dioxygen, Benzoic Anhydride, and Axial Ligands," 26 Inorg. Chem. 2612 (1987).
J. L. Bear, L. N. Liu and K. M. Kadish, "Structural, ESR, and Electrochemical Properties of Two[Rh.sub.2 (ap).sub.4 ].sup.+ Geometric Isomers (ap=2-Anilinopyridinate), A True Mixed-Valent Rhodium (III) Complex," 26 Inorganic Chem., 2927-7 (1987).
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D. A. Tocher and J. H. Tocher, "Synthesis and Spectro-Electrochemical Characterization of a Novel Rhodium (II) Dimer, Rh.sub.2 (phNpy).sub.4 ", 104, Inorganica Chimica Acta, L15-L17 (1985).
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