Refrigeration – Cryogenic treatment of gas or gas mixture – Separation of gas mixture
Reexamination Certificate
2002-12-16
2003-12-16
Doerrler, William C. (Department: 3744)
Refrigeration
Cryogenic treatment of gas or gas mixture
Separation of gas mixture
C062S654000, C062S905000
Reexamination Certificate
active
06662594
ABSTRACT:
The invention relates to an apparatus for producing gaseous oxygen under elevated pressure with a distillation column system, which has a high-pressure column and a low-pressure column, the low-pressure column being located above the high-pressure column, with a side condenser, which has a liquefaction space and a vaporization space and which is located below the bottom of the low-pressure column, with a feed air line, which is connected to the high-pressure column, with at least one transition line for introducing a fraction from the high-pressure column into the low-pressure column, with a liquid line for removing a liquid oxygen fraction from the low-pressure column, the liquid line leading into the vaporization space of the side condenser, and with a product line for gaseous oxygen under elevated pressure, which is connected to the vaporization space of the condenser-vaporizer.
The distillation column system, for example a Linde double-column system, is used for low-temperature separation of feed air into oxygen and nitrogen. The principles of low-temperature separation of air in general and the structure of the double-column system in particular are described in the monograph “Low-Temperature Technology” by Hausen/Linde (2nd Edition, 1985) and in an article by Latimer in Chemical Engineering Progress (Vol. 63, No. 2, 1967, page 35). The high-pressure column and the low-pressure column are generally in a heat exchange relationship via a main condenser in which the top gas of the high-pressure column is liquefied against the vaporizing bottom liquid of the low-pressure column.
An apparatus of the initially mentioned type is known from DE 2323941 A, EP 384483 B1 (U.S. Pat. No. 5,036,672) and EP 1074805 A1 (U.S. Pat. No. 6,332,337). The side condenser is used for vaporization. It is conventionally located next to the high-pressure column.
The distillation column system and the side condenser, generally also a main heat exchanger for cooling the feed air and optionally a supercooling countercurrent heat exchanger, must be insulated against the entry of heat. To do this, generally one or more powder (perlite)-filled jackets, so-called cold boxes, are used.
Here, the “side condenser” is a condenser-vaporizer, which is located outside the low-pressure column, and its vaporization side during system operation is under a higher pressure than the low-pressure column. The oxygen vaporized there is then obtained under a correspondingly increased pressure as a gaseous product. The pressure increase is caused by the geodetic gradient (and optionally in addition by a pump). The side condenser is preferably made as a liquid bath vaporizer (circulation vaporizer): A plate heat exchanger block contains vaporization and liquefaction passages. It is located in a tank, which is partially filled during operation with the liquid to be vaporized. The liquid is overturned by means of the thermosiphon effect through the vaporization passages of the plate heat exchanger block. The vaporization space is formed by these vaporization passages and by the outside space between the block and tank wall, and the liquefaction space is formed by the liquefaction passages.
An object of the invention is to provide an apparatus of the initially mentioned type which is especially economical and especially particularly compact.
Upon further study of the specification and appended claims, further objects and advantages of this invention will become apparent to those skilled in the art.
For this purpose, it was conventional in the past for all apparatus parts, even for the columns to be placed next to one another (see, for example, DE 19904526 or U.S. Pat. No. 6,148,637).
In accordance with the invention, these objects are achieved by locating the side condenser below the high-pressure column. “Below one another” here means that the cross sections of the two apparatus parts intersect in the projection onto the horizontal plane, “horizontal” relating to the orientation of these parts during operation. The cross sections of the side condenser and the high-pressure column overlap in this sense, for example, in part or completely. Preferably, the side condenser, the high-pressure column and the low-pressure column are located in a line below one another. A common cold box, which can encompass all three apparatus types, can thus be made especially compact and thus economical. Another advantage arises by the greater vertical distance between the low-pressure column and the side condenser. The pressure increase that arises solely by the gradient between the low-pressure column and side condenser is, therefore, without supplying energy from the outside, accordingly more dramatic. The gaseous oxygen product can therefore be obtained under an especially high pressure, for example, 1.5 to 3.5 bar, preferably 2 to 2.8 bar. Here, the operating pressure of the columns of the distillation column system (each at the top) is, for example, 5 to 9 bar, preferably 6.0 to 7.5 bar in the high-pressure column and, for example, 1.3 to 2.0 bar, preferably 1.5 to 1.8 bar in the low-pressure column.
Preferably, the low-pressure column, the high-pressure column and the side condenser are arranged in a line below one another.
Preferably, the feed air line is routed through the liquefaction space of the side condenser. The feed air is thus used as a heating means for the vaporization of the liquid oxygen fraction and in doing so partially or completely condenses.
Here, it is favorable if the feed air line and the side condenser are designed such that during operation of the device, the feed air is only partially condensed in the side condenser, for example, 30 mole % or less, preferably 25 to 30 mole %. Thus, on the one hand, all the feed air (optionally minus the amount of turbine air) can be routed through the side condenser, and other feed air lines are unnecessary. On the other hand, for only partial condensation, a higher vaporization temperature at the same pressure is reached; conversely, a lower air pressure is sufficient at the same oxygen product pressure. The pressure in the liquefaction space of the side condenser is preferably 6 to 8 bar. The partially condensed feed air from the side condenser can be fed into a separator (phase separator), which is located, for example, directly next to the side condenser within the cold box.
Any air separation system has a main heat exchanger for cooling the feed air against product flows. In the inventive device, it is favorable if this main heat exchanger is located below the high-pressure column, especially between the high-pressure column and the side condenser. In this way, the main heat exchanger can be encompassed by the common, compact cold box. Separate insulation and a bulky configuration of the box can be avoided. The additional height of the main heat exchanger entails an additional pressure increase in the oxygen product.
Often the feed liquid(s) for the low-pressure column is(are) supercooled against the gas product(s) of the low-pressure column by indirect heat exchange in a supercooling countercurrent heat exchanger. Within the framework of the invention, it is advantageous if this additional heat exchanger is located likewise between the high-pressure column and the side condenser. It can thus likewise be encompassed by a common, compact cold box. Separate insulation and a bulky configuration of the box can be avoided. The additional height of the main heat exchanger entails an additional pressure increase in the oxygen product.
Preferably, the apparatus parts are located directly on top of one another in the following sequence: side condenser (optionally with a separator)-supercooling countercurrent heat exchanger-main heat exchanger-high-pressure column-low-pressure column.
The invention relates, moreover, to a process for producing gaseous oxygen under elevated pressure. The process comprises:
introducing a feed gas into the high-pressure column;
introducing at least one fraction from the high-pressure column into the low-pressure column;
introducing a liquid oxygen fraction f
Lauter Michael
Rampp Augustin
Doerrler William C.
Linde Aktiengesellschaft
Millen White Zelano & Branigan P.C.
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