Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-08-04
1977-09-27
Lieberman, Paul
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260 459NC, 260 775AM, 260 775AQ, 260 75N, 260 78S, 260830P, 260857PE, 260858, C08L 7700
Patent
active
040511960
ABSTRACT:
It has been suggested that antistatic properties of fibers of polyamide could be improved by uniformly dispersing in the polyamide between about 1 percent and about 12 percent by weight of a predominantly branched, chain-extended propylene oxide-ethylene oxide copolymer based on a diamine. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of "nubs" or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer about 0.5 to 12% by weight, based on the weight of the antistatic agent, of a phenol compound represented by the formula: ##STR1## where n is 2 to 6. In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.
REFERENCES:
patent: 3584047 (1971-06-01), Dexter
patent: 3655821 (1972-04-01), Lofquist
patent: 3787523 (1974-01-01), Crescentini
patent: 3848023 (1974-11-01), Baggett
patent: 3882190 (1975-05-01), Wells
Crescentini Lamberto
Wells Rodney Lee
Allied Chemical Corporation
Kelly Fred L.
Lieberman Paul
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