Compositions: coating or plastic – Coating or plastic compositions – Inorganic settable ingredient containing
Reexamination Certificate
2003-01-09
2004-06-22
Green, Anthony J. (Department: 1755)
Compositions: coating or plastic
Coating or plastic compositions
Inorganic settable ingredient containing
C106S015050, C106S018310, C106S018320, C106S724000, C106S727000, C106S802000, C106S808000, C106S819000, C106S823000, C424S618000
Reexamination Certificate
active
06752867
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to an antibacterial agent for concrete and more particularly to an antibacterial agent possessing an effect of controlling or inhibiting sulfur reducing bacteria and sulfur oxidizing bacteria, which are causative bacteria for the corrosion of concrete in, for instance, sewage treatment plants. Moreover, the present invention likewise relates to a concrete composition and a concrete product containing the foregoing antibacterial agent for concrete.
BACKGROUND ART
There has long been known that structures and duct lines made of concrete are corroded by the action of hydrogen sulfide and/or sulfuric acid generated by or in, for instance, sewage treatment plants. It has been confirmed that this concrete corrosion is caused by the action of sulfuric acid, which is formed from sulfuric acid salts present in sewage through sulfurous acid salts and/or elemental sulfur by the action of sulfur oxidizing bacteria belonging to, for instance, the genus Thiobacillus and/or sulfur reducing bacteria belonging to, for instance, the genus Desulfovibrio. The sulfuric add thus formed may convert concrete into fragile or brittle substances such as gypsum through a chemical reaction to thus reduce the strength of the concrete structures and/or duct lines at a stroke and to consequently damage the same. Up to this time, there have been employed techniques for preventing or dealing with the corrosion of this type such as the ventilation, the incorporation of a neutralizing agent into the same and surface treatment with a corrosion-resistant material, but they are not considered to be satisfactory measures from the viewpoint of the prevention of corrosion over a long period of time and maintenance.
Subsequently, there has been proposed a technique for solving the foregoing problems, which comprises the step of incorporating, into a concrete composition, an organic agent such as thiabendazole, nickel metal (see the following Patent 1) possessing an antibacterial action against the sulfur reducing bacteria, or antibacterial metal ion-caring inorganic powder (see the following Patent 2) to thus prevent any corrosion of concrete. In particular, the technique in which antibacterial metal ion-carryying inorganic powder is incorporated into concrete is an effective technique since such antibacterial metal ion-carrying inorganic powder has a growth-inhibitory effect not only on sulfur oxidizing bacteria, but also on sulfur reducing bacteria and carboxylic acid-producing bacteria. Incidentally, it is necessary to control the mixing ratio of cement, aggregates and water contained in a concrete composition to a desired range in order to impart a desired strength to a resulting concrete structure. For this reason, a new problem arises such that the antibacterial metal ion-carrying inorganic powder cannot be incorporated into a concrete composition in an amount sufficient for imparting a required bacterial growth-inhibitory effect to the concrete structure.
[Patent 1]: Japanese Un-Examined Patent Publication No. Hei 4-149053 (upper right column, line 12 to lower left column, line 4 on page 2);
[Patent 2]: Japanese Un-Examined Patent Publication No. Hei 9-60768 (right column, lines 7 to 47 on page 2).
SUMMARY OF THE INVENTION
A first object of the present invention is to provide an antibacterial agent for concrete having excellent antibacterial effect against causative bacteria for the corrosion of concrete such as sulfur reducing bacteria, sulfur oxidizing bacteria and carboxylic acid-producing bacteria present, in particular, in sewage treatment plants.
A second object of the present invention is to provide an antibacterial agent for concrete, which can impart, to a concrete composition having any mixing ratio, an excellent antibacterial effect on the causative bacteria of the corrosion of concrete.
A third object of the present invention is to provide a concrete composition, which comprises the aforementioned antibacterial agent for concrete.
A fourth object of the present invention is to provide a concrete product, which comprises the foregoing antibacterial agent for concrete.
A fifth object of the present invention is to provide a concrete product prepared using the foregoing antibacterial agent for concrete.
According to the present invention, there are provided an antibacterial agent for concrete, a concrete composition and a concrete product which are described below.
1. An antibacterial agent for concrete comprising a silver compound, a copper compound and an ion-retaining compound.
2. The antibacterial agent for concrete of the foregoing item 1 wherein the silver compound is at least one member selected from the group consisting of silver carbonate, silver oxide and silver phosphate.
3. The antibacterial agent for concrete of the foregoing item 1 or 2 wherein the copper compound is at least one member selected from the group consisting of copper carbonate, copper oxide, copper phosphate and copper hydroxide.
4. A concrete composition comprising an antibacterial agent for concrete as set forth in any one of the foregoing items 1 to 3.
5. A concrete product comprising an antibacterial agent for concrete as set forth in any one of the foregoing items 1 to 3.
6. A concrete product characterized in that it is produced using a concrete composition of the foregoing item 4.
BEST MODE FOR CARRYING OUT THE INVENTION
According to the present invention, there is provided an antibacterial agent for concrete, which comprises a silver compound, a copper compound and an ion-retaining compound.
In the present invention, an antibacterial agent for concrete can be prepared and the antibacterial agent permits the impartment of sufficient antibacterial properties to a concrete composition having any mixing ratio, if incorporating, into the antibacterial agent, a silver compound and a copper compound having high content of silver and copper respectively, as concrete corrosion-inhibitory components. Moreover, the incorporation of an ion-retaining compound into the agent of the present invention would permit the effective control of the liquation of the useful silver and copper components and the maintenance of the excellent antibacterial effect over a long period of time.
Therefore, the antibacterial agent for concrete according to the present invention inhibits the corrosion of concrete by the action of bacteria over a long period of time and thus permits the maintenance of the normal state of the concrete product.
The silver compounds used in the present invention are not restricted to specific ones inasmuch as they contain silver and these compounds are preferably those comprising a large quantity of silver, for instance, it is desirable to use those comprising silver in an amount of not less than 40% by mass, more preferably not less than 60% by mass and most preferably not less than 75% by mass. Examples of silver compounds preferably used in the present invention are silver carbonate (silver content: 78%), silver oxide (silver content: 93%), silver phosphate (silver content: 87%), silver chloride (silver content: 75%), silver fluoride (silver content: 85%), silver iodide (silver content: 46%), silver bromide (silver content: 57%), silver nitrate (silver content: 63%), silver sulfate (silver content: 69%), silver acetate (silver content: 65%), silver oxalate (silver content: 71%) and silver zeolite (for instance, those having a silver content of 5%). Among these examples, particularly preferred are silver carbonate, silver oxide and silver phosphate since these compounds are appropriately dissolved in sewage when they come in contact with the latter and they are liable to show their antibacterial effects therein. In this connection, a standard for the solubility of the compound in sewage when it comes in contact with the sewage is preferably set up at a level falling within the range of from 10 to 1000 ppm as expressed in terms of the solubility of silver in an artificial sewage.
The composition of such an artificial sewage is as follows: peptone: 6
Kamiike Yuji
Kurihara Yasuo
Takahashi Javier
Green Anthony J.
Sinanen Zeomic Co., Ltd.
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