Anthracycline synthesis

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260376, 260377, 260365, 568633, 560 52, C07C 5018, C07C 5016, C07C10180, C07C10375

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active

042448808

ABSTRACT:
A process for synthesizing the 7-substituted or unsubstituted 5,12-dihydroxy-1,2,3,4,6,11-hexahydro-2,6,11-trioxonaphthacene precursors for doxorubicin and related compounds from butadiene and p-benzoquinone and intermediates useful in the synthesis.

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patent: 4021457 (1977-05-01), Kende et al.
patent: 4116981 (1978-09-01), Kende
Chemical Abstracts, vol. 83, #210755g, Wayne et al., "Electrochemical Reactions of Organic Compounds in Ammonia III Reductive Alkylation of Quinoline", 1975.
Chemical Abstracts, vol. 81, #37348, Tashiro et al., "Positional Protective Groups on Aromatic Rings I New Preparative Method for Halophenols With Tert-butyl or Benzyl Group as a Protective Group," 1974.
Chemical Abstracts, vol. 86, #120900r, Meider et al., "Specific Ortho-bromination I Preparation of Ortho-bromo Substituted benzenes, " 1977.
Journal of the American Chemical Society, vol. 99, p. 5513, "Synthetic Approaches to Adriamycin", Kelly et al., 1977.
Tetrahedron Letters, No. 28, p. 2323, "A Regiospecific Synthesis of Anthracyclinones", Swenton et al., 1977.
Journal of Organic Chem., vol. 41, No. 13, pp. 2296-2301, "Daunomycinone Analogues via Diels-Alder Reaction", Lee et al., 1976.

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