Anisotropic compounds with negative or positive DC-anisotropy an

Compositions – Liquid crystal compositions – Containing nonsteryl liquid crystalline compound of...

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2522995, 260465D, 260465R, 260465G, 260465H, 260465F, 560 1, 560 20, 560 21, 560 23, 560 59, 560 61, 560 62, 560 64, 560 65, 560 73, 560102, 560106, 560107, 560118, 560126, 568585, 568631, 568642, 568648, 568649, 568656, 568659, 568661, 570129, 570182, C09K 334, C07C12175

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043681352

ABSTRACT:
Anisotropic compounds with negative or positive DCA and .DELTA.n.ltoreq.0.2 have the formula (1) ##STR1## in which R.sup.1 and R.sup.2 l are independently hydrogen, alkyl, alkoxy having 1 to 12 carbon atoms respectively, or one of R.sup.1 and R.sup.2 can represent cyclical fragment of formulae (1a) or (1b); ##STR2## the bridges Z.sup.1, Z.sup.2 and Z.sup.3 are identical or different and means covalent bonds or carboxyl or oxycarbonyl groups; R.sup.3 is hydrogen, alkyl or alkoxy group having 1 to 12 carbon atoms, respectively; X.sup.1 and X.sup.4 are independently hydrogen, halogen, nitrile or nitro, wherein at least one of X.sup.1 and X.sup.4 is not hydrogen when R.sup.2 represents a cyclical fragment of formula (1a) or (1b) and Z.sup.2 is a carboxyl group or Z.sup.3 is an oxycarbonyl group, respectively. Liquid crystal compositions are also disclosed.

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Dewar, M. J. S., et al.; JACS, vol. 92, No. 6, pp. 1582-1586 (1970).
Demus, D., et al., Mol. Cryst. Liq. Cryst., vol. 63, pp. 129-144 (1981).
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