Anhydrous hydrogen chloride evolving one-step process for produc

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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556452, 556456, C07F 708

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active

050754793

ABSTRACT:
The instant invention is a one-step process for producing polydiorganosiloxanes (siloxanes). In the described process, a mixture comprising diorganodichlorosilane and a source of triorganosilyl groups is contacted with excess water essentially saturated with hydrogen chloride. Product siloxanes are isolated as well as saturated aqueous hydrogen chloride and anhydrous hydrogen chloride. The amount of triorganosilyl groups present in the mixture is controlled to set the degree of polymerization of product siloxanes. The isolated saturated aqueous hydrogen chloride is recycled to the process. Excess chloride generated in the process is collected as anhydrous hydrogen chloride.

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