Anhydrous cerous nitrate-ammonium nitrate complex and a process

Details Anhydrous cerous nitrate-ammonium nitrate complex and a process Anhydrous cerous nitrate-ammonium nitrate complex and a process

1988-01-14

1989-01-24

Doll, John

Chemistry of inorganic compounds

Nitrogen or compound thereof

Oxygen containing

423397, C06B 104

Patent

active

048000728

ABSTRACT:
A procedure for preparing anhydrous cerous nitrate ammonium nitrate complex comprising treating dried anhydrous ceric hexanitro ammonium complex (ceric ammonium nitrate) with a reducing agent such as ammonia whereby Ce.sup.+4 is reduced to Ce.sup.+3 under anhydrous conditions. The resulting Ce.sup.+3 species, a complex of Ce.sup.+3 nitrate and ammonia nitrate, can be used as a source of anhydrous Ce.sup.+3 ions.

REFERENCES:
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patent: 2166702 (1939-07-01), Blumenfeld
patent: 3100683 (1963-08-01), Roberts
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patent: 4489000 (1984-12-01), Gradeff et al.
patent: 4492655 (1985-01-01), Gradeff et al.
Gmelin Handbuch der Chimie, German Version and Translation, p. 293 (date: before 1988).
Communist Chinese Sci. Abstr., Chem. 3(Oct.), 9 (1965), Translation.
Chizhikov et al, Russian Journal of Inorganic Chemistry, pp. 1373-1377, (Nov. 1965).

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