Analytical spectroelectrochemistry

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250458, 356 36, 356 72, 356 96, G01J 342, G01N 2152

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039471241

ABSTRACT:
In a method of analytical spectrometry, material to be analysed is introduced in solution between a pair of charged electrodes so as to produce a light-absorbing atomic or molecular species by electrolysis at an electrode surface. A beam of light of an appropriate wavelength is directed through the solution into the vicinity of the relevant surface and light emerging from this vicinity is detected. Specific forms of apparatus are described for practising the method, using either absorption or fluorescence techniques.

REFERENCES:
strojek et al., Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 16, Apr. 1968, pp. 471-483.
Laser et al., Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 35, Mar. 1972, pp. 405-414.
Gruver et al., Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 36, Apr. 1972, pp. 85-99.
Prostak et al., The Journal of Physical Chemistry, Vol. 72, No. 7, July 1968, pp. 2576-2582.
Tallant et al., Analytical Chemistry Vol. 41, No. 6, May 1969, pp. 835-838.

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