Analytical method and apparatus for analyzing substances

Chemistry: analytical and immunological testing – Measurement includes change in volume or pressure

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422 67, 422 681, 422 81, 436158, 436181, G01N 2514

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active

052702189

ABSTRACT:
An analytical method which comprises sampling a predetermined amount of a liquid sample, bringing the sample to a vapor-liquid equilibrium at a predetermined temperature and pressure, separating the resultant gaseous and liquid fractions from each other, and analyzing the gaseous fraction as a gas sample and the liquid fraction as a liquid sample, and an apparatus for practicing the analytical method. By this method or apparatus, the light and heavy fractions of a substance can be simultaneously analyzed in composition and chemical structure. This enables the modification and the service life of a chemical substance like a lubricating oil, in which the qualities may change with the passage of time, to be estimated or foreseen.

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Poole, et al., J. High Resolution Chrom. & Chrom. Comm., vol. 6, Oct. 1983, pp. 537-539.
Karasek, et al., Anal. Chem. (1984) vol. 56 p. 192R.
Walas, Phase Equilibria in Chemical Engineering, Butterworth Publishers, Boston (1985) pp. 534-535.

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