AMS-1B crystalline borosilicate molecular sieve-based catalyst c

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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C07C 268

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active

046737677

ABSTRACT:
Described are catalyst compositions comprising a HAMS-1B crystalline borosilicate molecular sieve incorporated into an inorganic matrix, which have been impregnated with a magnesium compound or with both a phosphorus compound and a magnesium compound, said impregnated compositions having improved para-selectively for toluene alkylation. Such impregnated compositions, when used for the alkylation of toluene using methanol, methylether, ethylene, or propylene yield dialkylbenzene products containing a higher proportion of the para-isomer than corresponding unimpregnated borosilicate-based compositions. When toluene is alkylated with propylene using the impregnated catalyst compositions of this invention, a significant increase in para-selectivity among the cymene isomers is obtained at high total-cymene
-propyltoluene ratios.

REFERENCES:
patent: 4491678 (1985-01-01), Oda et al.

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