Amphoteric styrene derivatives useful as fluorescent brighteners

Bleaching and dyeing; fluid treatment and chemical modification – Dye or potential dye composition – additive – treatment,... – Fluorescent dye – e.g. – stilbene – benzimidazole – benzoxazole,...

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252 875, 252 88, 25230121, 25230135, 252524, 252526, 252527, 252543, 252545, 252546, 260459A, 260465D, 427158, 546255, 260239B, 544111, 544158, 544159, 544169, 544172, 544174, 544357, 544359, 546192, 546208, 548518, 548531, C11D 342, D06L 312

Patent

active

044785984

ABSTRACT:
The amphoteric styrene derivatives correspond to the formula ##STR1## in which X is oxygen, sulfur, a direct bond, --SO.sub.2 N(R.sub.5 --, --CON(R.sub.5 -- or --COO--, Y.sub.1 and Y.sub.2 independently of one another are C.sub.1 -C.sub.4 -alkylene or hydroxypropylene, R.sub.1 and R.sub.2 independently of one another are C.sub.1 -C.sub.4 -alkyl or, together with the N atom, are a pyrrolidine, piperidine, hexamethyleneimine or morpholine ring, and R.sub.1, together with R.sub.5, is also a piperazine ring, R.sub.3 and R.sub.4 are hydrogen, C.sub.1-4 -alkyl, chlorine, C.sub.1-4 -alkoxy or C.sub.3-4 -alkenyl or together, in the o-position relative to one another, are a trimethylene or tetramethylene group, R.sub.5 is hydrogen, C.sub.1-4 -alkyl or cyanoethyl or, together with R.sub.1, is a piperazine ring, Q is --COO or --SO.sub.3 and n is the number 1 or 2, and can be prepared by reacting the corresponding amine compounds with a halide of the formula Hal--Y.sub.2 --QH and saponifying the quaternary ammonium halides eventually formed. They can be used for the fluorescent brightening of organic materials.

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