Amorphous hydrated metal oxide primer for organic adhesively bon

Stock material or miscellaneous articles – Composite – Of inorganic material

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156314, 156319, 427337, B32B 900, C09J 504

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active

048533009

ABSTRACT:
An amorphous hydrated metal oxide primer for adhesively bonded articles results in a bond resistant to crack propagation. A plurality of articles at least one of which is ceramic are bonded to one another through a layer of polymeric adhesive. The ceramic article has a layer of amorphous hydrated metal oxide formed by applying and subsequent hydrolysis of a layer comprising M.sub.x OR.sub.y or mixtures thereof. In the formula M.sub.x OR.sub.y, x is 1, y is 3 or 4, M is any metal capable of forming a stable alkoxide and R is an organic radical. The bonded joint is preferably made by applying to a surface of at least one ceramic article a layer of M.sub.x OR.sub.y described above. The ceramic article having a layer of metal alkoxide is exposed to moisture and a temperature of about 25.degree. C. to about 300.degree. C. and adhesive is placed in contact with and between the ceramic article and other article. The two bonded articles are then exposed to pressure and optional heat resulting in a joint resistant to crack propagation.

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patent: 4085012 (1978-04-01), Marceau et al.
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patent: 4532179 (1985-07-01), Takami et al.
patent: 4562104 (1985-12-01), Maeda
patent: 4623591 (1986-11-01), Pike
Pike, "Inorganic Primers to Bonded Joints and Fiber Reinforced Resin Composites", International Adhesion Conference, 9-1984.
Paper presented at The International Adhesion Conference 1984 titled "Inorganic Primers in Bonded Joints and Fiber Reinforced Resin Composites" by Roscoe A. Pike, Sep. 12-14, 1984, University of Nottingham, London, England.

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