Ammoxidation of olefins with novel antimonate catalysts

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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2604653, 585431, 585616, 585621, 585622, 585623, 585624, 585625, 585626, 585631, C07C 1112

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active

044131550

ABSTRACT:
Oxide complex catalysts comprising Fe-Sb-Bi-O.sub.x promoted with a wide variety of different elements have been found to be especially useful in the ammoxidation of olefins to nitriles such as acrylonitrile and methacrylonitrile. Not only are the desired nitriles obtained with high yields when these catalysts are used, but also the production of unwanted liquid byproducts such as acrolein, acrylic acid and acetonitrile is significantly reduced.

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