Ammonium hydroxide stripping of tungsten from organic solvents

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

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423 53, 75101BE, C01G 4100

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active

044501447

ABSTRACT:
A process for stripping tungsten values from a tungsten-bearing acidic liquid organic phase into a basic aqueous ammoniacal stripping solution comprises mixing the organic phase and the stripping solution with a high-shear mixing device to maximize the pH gradient between the organic phase and the aqueous solution whereby growth of any precipitated ammonium paratungstate crystals is minimized and the dissolution thereof is maximized and to strip the tungsten values from the organic phase into the stripping solution.

REFERENCES:
patent: 3158438 (1964-11-01), Kurtak et al.
patent: 4092400 (1978-05-01), Zbranek et al.
patent: 4148862 (1979-04-01), Fugleberg et al.
Yih & Wang, Tungsten: Sources, Metallurgy, Properties & Applications, (1979), p. 108.
Petrov, Maslenitskii, et al., "Using Amines to Extract Tungsten . . . ", Tsvetnye Metally, V. 11-19, (1970), pp. 45-56.
Parker, "Mixing . . . ", in Chemical Engineering, 71 (12), Jun. 8, 1964, pp. 165-220.

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