Ammonia synthesis with catalyst derived by heating on a support

Chemistry of inorganic compounds – Nitrogen or compound thereof – Ammonia or ammonium hydroxide

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423363, C01C 104

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043483704

ABSTRACT:
Synthesis of ammonia employing at least one salt selected from alkali metal-, an alkaline earth metal-, iron- and cobalt hexacyanocobaltate and hexacyanoruthenate on a suitable support and then heating the composition to provide it with suitable activity.

REFERENCES:
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patent: 1352180 (1920-09-01), Clancy
patent: 3678085 (1972-07-01), Rick et al.
patent: 3904737 (1975-09-01), Paris et al.
patent: 3909247 (1975-09-01), Paris et al.
patent: 4163775 (1979-08-01), Foster et al.
Simon et al., "Preparation and Structure of Barium Decacyanodicobaltate (II) Tridecahydrate, Ba.sub.3 [CO.sub.2 (CN).sub.10 ].13H.sub.2 O, Stereochemical Analysis of the Metal--Metal Bonded [CO.sub.2 (CN).sub.10 ].sup.6t " Dimer, Journal of the American Chemical Society 94:22 (Nov. 1, 1972), pp. 7654-7663.

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