Ammonation of trialkanolamines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564499, C07C 8900

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active

043283705

ABSTRACT:
Lower trialkanolamines such as triethanolamine and triisopropanolamine are converted to the corresponding mono- and dialkanolamine by reacting with ammonia at about 150.degree. C.-275.degree. C. under superatmospheric pressure in the presence of a hydrogenation catalyst. The process is particularly useful for the recovery of alkanolamine values from still bottoms of alkanolamine production processes.

REFERENCES:
patent: 2112970 (1938-04-01), Millington
patent: 2192523 (1940-03-01), Olin et al.
patent: 2861995 (1958-11-01), MacKenzie
patent: 2910477 (1959-10-01), Long
patent: 3068290 (1962-12-01), Lichienberger et al.
patent: 3270059 (1966-08-01), Winderl et al.
patent: 3520933 (1970-07-01), Adam et al.

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