Aminopyridyl silanes

Details Aminopyridyl silanes Aminopyridyl silanes

1990-01-18

1991-03-05

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C09F 710

Patent

active

049979442

ABSTRACT:
Silanes and siloxanes incorporating the 4-dialkylaminopyridine functionality are described. Preferred silanes are catalytically active and also serve as precursors to the siloxanes. Preferred siloxanes incorporating DAAP functionality exhibit excellent physical and dynamic-mechanical properties while maintaining a substantial percentage of the DAAP catalytic behavior.

REFERENCES:
patent: 2854455 (1958-09-01), Cislak
patent: 4855433 (1989-08-01), Zeldin
patent: 4864027 (1989-09-01), Shubert et al.
Frechet et al., "Reactive Polymers: Design Considerations, Novel Preparations and Selected Applications in Organic Chemistry" Pure Appl. Chem., 1988, 60, 353.
Menger et al., "A Polymer-Bound 4-Aminopyridine; Synthesis and Reactivity," J. Org. Chem., 1985, p. 3928.
Mathias et al., "Synthesis, Chclopolymerization, and Cyclocopolymerization of 4-(Diallylamino)Pyridine: A New Monomer" J. Polym. Lett. Ed. 1985, 23, 147.
Mathias et al., "Inverse Phase Transfer Catalysis, First Report of a New Class of Interfacial Reactions" J. Am. Chem. Soc. 1986, 108, 1093-1094.
Vaidya et al., "Polymeric Supernucleophilic Pyridine Catalysts: Homogeneous Esterolysis of p-Nitrophenyl Esters" J. Am. Chem. Soc. 1986, 108, 5514-5520.

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