Aminoalkyllithium compounds containing cyclic amines and polymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From hydrocarbon reactant

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

528406, 528417, 528422, 528423, C08G 6100

Patent

active

060808357

ABSTRACT:
A functionialized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.

REFERENCES:
patent: 2849432 (1958-08-01), Kibler et al.
patent: 3109871 (1963-11-01), Zalinski et al.
patent: 3177190 (1965-04-01), Hsieh
patent: 3178398 (1965-04-01), Strobel et al.
patent: 3240772 (1966-03-01), Natta et al.
patent: 3290277 (1966-12-01), Anderson et al.
patent: 3317918 (1967-05-01), Foster
patent: 3326881 (1967-06-01), Uraneck et al.
patent: 3331821 (1967-07-01), Strobel
patent: 3393182 (1968-07-01), Trepka
patent: 3426006 (1969-02-01), Nutzel et al.
patent: 3439049 (1969-04-01), Trepka
patent: 3856877 (1974-12-01), Otsuki et al.
patent: 3935177 (1976-01-01), Muller et al.
patent: 3976628 (1976-08-01), Halasa et al.
patent: 4015061 (1977-03-01), Schulz et al.
patent: 4026865 (1977-05-01), Uraneck et al.
patent: 4085265 (1978-04-01), Otsuki et al.
patent: 4247418 (1981-01-01), Halasa et al.
patent: 4316001 (1982-02-01), Boileau et al.
patent: 4383085 (1983-05-01), Fujimaki et al.
patent: 4402844 (1983-09-01), Trepka
patent: 4414372 (1983-11-01), Farnham et al.
patent: 4429091 (1984-01-01), Hall
patent: 4476240 (1984-10-01), Hall et al.
patent: 4478953 (1984-10-01), Yuki et al.
patent: 4515922 (1985-05-01), Sakakibara et al.
patent: 4614771 (1986-09-01), Watanabe et al.
patent: 4616069 (1986-10-01), Watanabe et al.
patent: 4647634 (1987-03-01), Jalics
patent: 4677153 (1987-06-01), Kitahara et al.
patent: 4713424 (1987-12-01), Brown
patent: 4734461 (1988-03-01), Roggero et al.
patent: 4735994 (1988-04-01), Rogger et al.
patent: 4736003 (1988-04-01), Schneider et al.
patent: 4791174 (1988-12-01), Bronstert et al.
patent: 4816520 (1989-03-01), Bronstert
patent: 4835209 (1989-05-01), Kitagawa et al.
patent: 4843120 (1989-06-01), Halasa et al.
patent: 4894409 (1990-01-01), Shimada et al.
patent: 4914147 (1990-04-01), Mouri et al.
patent: 4931376 (1990-06-01), Ikematsu et al.
patent: 4935471 (1990-06-01), Halasa et al.
patent: 4978754 (1990-12-01), Ibi et al.
patent: 5066729 (1991-11-01), Stayer, Jr. et al.
patent: 5112929 (1992-05-01), Hall
patent: 5115035 (1992-05-01), Shiraki et al.
patent: 5149457 (1992-09-01), Smith
patent: 5153159 (1992-10-01), Antkowiak et al.
patent: 5153271 (1992-10-01), Lawson et al.
patent: 5196138 (1993-03-01), Smith, Jr.
patent: 5292790 (1994-03-01), Shimizu et al.
patent: 5349024 (1994-09-01), Hergenrother et al.
patent: 5496883 (1996-03-01), Hamada
patent: 5523364 (1996-06-01), Engel et al.
patent: 5527753 (1996-06-01), Engel et al.
patent: 5550203 (1996-08-01), Engel et al.
patent: 5587420 (1996-12-01), Takizawa et al.
patent: 5605872 (1997-02-01), Engel et al.
patent: 5626798 (1997-05-01), Schwindeman et al.
patent: 5663398 (1997-09-01), Schwindeman et al.
patent: 5718877 (1998-02-01), Manev et al.
patent: 5726308 (1998-03-01), Hall et al.
patent: 5736617 (1998-04-01), Kerns et al.
patent: 5786441 (1998-07-01), Lawson et al.
"3-Dimethylaminopropyl-Lithium-An Analytical and Kinetic Investigation of a New Initiator System for Polymer Synthesis" by Eisenbach et al., European Patent Journal, vol. 11, pp. 699-704 (1975).
"A Bifunctional Anionic Initiator Soluble in Non-polar Solvents" by Beinert et al., Makromol. Chem 179, pp. 551-555 (1978).
"An Improved Synthesis of P-Dimethylaminophenyl-Lithium" by Hallas et al., Chemistry and Industry, p. 620 (1969).
"Anionic Polymerization. VII Polymerization and Copolymerization with Lithium Nitrogen-Bonded Initiator" by Cheng, American Chemical Society, pp. 513-525 (1981).
"Anionic Polymerization Initiators containing Protected Functional Groups and Functionally Terminated Diene Polymers" by Schulz et al., Journal of Polymer Science: Polymer Chemistry Edition, vol. 12, pp. 153-166 (1974).
"Anionic Polymerization Initiated by Diethylamide in Organic Solvents. I. The Use of Lithium Diethylamide as a Polymerization catalyst and the effect of Solvent Type on the Polymerization of Isoprene and Styrene" by Angood et al., journal of Polymer Science: Polymer Chemistry Edition, vol. 11, pp. 2777-2791 (1973).
"Anionic Polymerization Initiators Containing Protected Functional Groups. II." by Schulz et al., Journal of Polymer Science: Polymer Chemistry Edition, vol. 15, pp. 2410-2410 (1977).
"Bifunctional Anionic Initiators: A Critical Study and Overview" by Bandermann et al., Makromol. Chem 186, pp. 2017-2025 (1985).
"Butadiene-Styrene Copolymerization Initiated by n-BuLi/THF/t-AmOK", by Lehong et al., Journal of Applied Polymer Science, vol. 44, pp. 1499-1505 (1992).
"6001 Chemical Abstracts", vol. 91, pp. 59 (1979).
"Copolymerization of Butadiene and Styrene by Initiation with Alkyllithium and Alkai Metal tert-Butoxides" by Wofford et al., Journal of Polymer Science: Part A-1, vol. 7, pp. 461-469 (1969).
"Lithium Amide Catalyzed Amine-Olefin Addition Reactions" by Schlott et al., J. Org. Chem., vol. 37, No. 26, pp. 4243-4245 (1972).
"New Perfectly Difunctional Organolithium Initiators for Block Copolymers Synthesis: Synthesis of Dilithium Initiators in the Absence of Polar Additives", by Guyot et al., Polymer, vol. 22 (1982).
"Polymerization of Unsaturated Compounds in the Presence of Lithium Diethylamide" by Vinogradov et al., Polymer Science U.S.S.R., vol. 4, pp. 1568-1572 (1963).
"Ortho Lithiation via a Carbonyl Synthon" by Harris et al., J. Org. Chem., vol. 44, No. 12, pp. 2004 & 2006 (1979).
"Preparation and Reactions of Trialkyltinlithium" by Tamborski et al., pp. 237-239, Jan. 1963.
"Preparation of Some Trialkyltin-Lithium Compounds" by Gilman et al., J. Am. Chem. Soc. 75, pp. 2507-2509 (1953).
"Some Reactions of Tributyl- and Triphenyl-Stannyl Derivatives of Alkali Metals" by Blake et al., J. Chem. Soc., pp. 618-622 (1961).
"Specific Functionalization of Polymers by Carboxyl Groups" by Broze et al., Makromol. Chem. 179, pp. 1383-1386 (1978).
"Stereospecific Addition Reaction Between Butadiene and Amines" by Imai et al., Tetrahedron Letters No. 38, pp. 3317-3520 (1971).
"Studies of the Anionic Polymerization of Phenyl Vinyl Sulfoxide and its Copolymer with Styrene" by Kanga et al., Macromolecules 23, pp. 4235-4240 (1990).
"Synthesis of New Monomers by Addition Reactions of Diethylamine to 1,4-Divinylbenzene Catalyzed by lithium Diethylamide" by Tsuruta et al., Makromol. Chem. 177, pp. 3255-3263 (1976).
"The Microstructure of Butadiene and Stryrene Copolymers Synthesized with n-BuLi/THF/t-AmOK" by Lehong et al., Journal of Applied Polymer Science, vol. 44, pp. 1507-1511 (1992).
"Thermal Elimination of Poly(phenyl vinyl sulfoxide) and Its Polystyrene Block Copolymers" by Kanga et al., Macromolecules 23, pp. 4241-4246 (1990).
One page translation of Japanese Abstract, Japanese Patent Application 87-180892/26.
One page Derwent Abstract of Japanese patent JP54065788.
"Metalations of Benzyldimethylamine and Related Amines with n-Butyllithium in Ether. Deuteration to Form Ring and Side-Chain Derivatives" by Jones et al., J. Org. Chem. 23, pp. 663-665 (Mar. 1963).
U.S. Patent Application Serial No. 08/777,657, filed on Dec. 31, 1996, entitled "Novel Tertiary Amines Containing Side-Chain Organolithium Structures and Method for the Preparation Thereof" by Lawson et al.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Aminoalkyllithium compounds containing cyclic amines and polymer does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Aminoalkyllithium compounds containing cyclic amines and polymer, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Aminoalkyllithium compounds containing cyclic amines and polymer will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1785468

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.