Amine-resin supported rhodium-cobalt carbonyl bimetallic cluster

Details Amine-resin supported rhodium-cobalt carbonyl bimetallic cluster Amine-resin supported rhodium-cobalt carbonyl bimetallic cluster

1977-06-06

1979-03-13

Garvin, Patrick

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252431N, 568819, 568909, 568883, B01J 3106, B01J 3128

Patent

active

041441915

ABSTRACT:
Olefins are converted to alcohols by a one-step, hydroformylation process comprising contacting an olefin, such as 1-hexene, with a gaseous mixture of carbon monoxide and hydrogen in the presence of a catalyst prepared by loading a bimetallic cluster of the formula: Rh.sub.x Co.sub.y CO.sub.12 wherein both x and y are independently integers 1-3 with the proviso that .SIGMA. (x+y)=4, onto an amine resin, such as Dowex.RTM. MWA-1.

REFERENCES:
patent: 3488333 (1970-01-01), Lefebure et al.
patent: 3636159 (1972-01-01), Solomon
patent: 3652676 (1972-03-01), Kahle et al.
patent: 3968136 (1976-07-01), Walker et al.
patent: 3996164 (1976-12-01), Matsuda
patent: 3998887 (1976-12-01), Allen
patent: 4013700 (1977-03-01), Cawse
patent: 4045493 (1977-08-01), Trevillyan
Jurewicz et al., Adv. Chem. Ser., 132, 240-251(1974).

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