Amine-resin supported rhodium-cobalt bimetallic clusters as nove

Details Amine-resin supported rhodium-cobalt bimetallic clusters as nove Amine-resin supported rhodium-cobalt bimetallic clusters as nove

1978-10-18

1980-04-08

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

560263, 568820, 568831, 568816, 568832, 568852, C07C 2900

Patent

active

041974140

ABSTRACT:
Olefins are converted to alcohols by a one-step, hydroformylation process comprising contacting an olefin, such as 1-hexene, with a gaseous mixture of carbon monoxide and hydrogen in the presence of a catalyst prepared by loading a bimetallic cluster of the formula: Rh.sub.x Co.sub.y CO.sub.12 wherein both x and y are independently integers 1-3 with the proviso that .SIGMA.(x+y)=4, onto an amine resin, such as Dowex.RTM. MWA-1.

REFERENCES:
patent: 3488333 (1970-01-01), Lefebvre et al.
patent: 3594425 (1971-07-01), Brader et al.
patent: 3636159 (1972-01-01), Solomon
patent: 4072720 (1978-02-01), Haag et al.

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