Amine/propylene copolymers

Details Amine/propylene copolymers Amine/propylene copolymers

1989-10-16

1993-08-24

Smith, Edward J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526125, C08F23008, C08F22602

Patent

active

052390306

ABSTRACT:
Mono and diallyl amines are silylated to protect them from reacting with high activity Ziegler-Natta catalysts so they may be copolymerized with propylene; copolymers of such amines with propylene and their hydrolyzed or alcholyzed counterparts; also the amine monomers disclosed.

REFERENCES:
patent: 2926161 (1960-02-01), Butler et al.
patent: 3131990 (1964-05-01), Bonvicini et al.
patent: 3412019 (1968-11-01), Hoover et al.
patent: 3445387 (1969-05-01), Liston
patent: 3533731 (1970-10-01), Sehmidl et al.
patent: 4439580 (1984-03-01), Schaper
Giannini et al, Stereospecific Polymerization of Monomers Containing Oxygen and Nitrogen with Ziegler-Natta Catalysts, Polymer Letters, vol. 5, pp. 527-533, (1967).
"O-Trimethylsilyl-Allyl Alcohol" formula, Petrarch Systems, Bristol, Pa., p. 146.
Giannini et al, Polymerization of Nitrogen-Containing and Oxygen-Containing Monomers by Ziegler-Natta Catalysts, J. Polymer Sci.:Part C22, pp. 157-175, (1968).
PCT International Publication Number WO 88/08856 (also identified as International Application Number PCT/US87/03454), Sivak et al, "Incorporation of Functional Groups in Polymers", Nov. 17, 1988, pp. 1-56.

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