Amine heat stable salt neutralization having reduced solids

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564497, 544358, 544384, C07C21500, C07C20900, C07D24104

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active

059123877

ABSTRACT:
A process is disclosed for the neutralization of amine or alkanolamine heat stable salts with aqueous KOH or with alkali metal base, such as potassium hydroxide, sodium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate or potassium bicarbonate formulated with amines or alkanolamines. The process results in less solid formation than commonly used alkali metal bases such as aqueous sodium hydroxide or aqueous potassium carbonate.

REFERENCES:
AN-010298, WPIDS, SU 1,426,072 (CAS Online Printout).
P. C. Rooney et al, Effect of heat stable salts on MDEA solution corrosivity, New Testing gives recommended limits of each species and the impact of temperature and pH, pp. 95-104, Hydrocarbon Processing, Mar. 1996.
P. C. Rooney et al, Effect of heat stable salts on MDEA solution corrosivity of MDEA-Based Alkanolamine Plants, Part II, Proceedings of the 1996 Laurance Reid Gas Conditioning Conference, Norman, OK, Mar. 4-6, 1996.
P. C. Rooney et al and K. D. Wilbanks, Effect of Chloride on Solution Corrosivity of Methyldiethanolamine (MDEA) Solutions, Paper No. 345, 1997 by NACE International Conference to be held Mar. 1997.
P. C. Rooney et al, Effect of heat stable salts on MDEA solution corrosivity of MDEA-Based Alkanolamine Plants, Part III, Proceedings of the 1997 Laurance Reid Gas Conditioning Conference to be held Mar. 1997..

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