Ambient-temperature superconductor symetrical metal-dihalide bis

Details Ambient-temperature superconductor symetrical metal-dihalide bis Ambient-temperature superconductor symetrical metal-dihalide bis

1985-05-29

1987-06-23

Jiles, Henry R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

428470, C07D40904, B32B 1100, B32B 1504

Patent

active

046754156

ABSTRACT:
A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K. which is high for organic superconductors.

REFERENCES:
Yagubskii et al., JETP Lett., 39, No. 1, (1984), pp. 12-16.
Shibaeva et al., Mol. Cryst. Liq. Cryst. 119 (1985), pp. 361-373.
Williams et al., Inorganic Chemistry 23(24), p. 3839 (1984).
Engemyr et al., Acta. Chem. Scan. A28 (1974), pp. 255-266.
Huheey, Inorganic Chemistry "Textbook", Harper and Row, Publishers (1972), pp. 184-185.
Crabtree et al., Physical Review B, 30, No. 5, (1984), pp. 2958-2960.
Braunstein et al., J. Chem. Soc. Dalton Trans. (1973), pp. 1845-1848.

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