Aluminum chloride catalyzed isomerization of sym-octahydrophenan

Details Aluminum chloride catalyzed isomerization of sym-octahydrophenan Aluminum chloride catalyzed isomerization of sym-octahydrophenan

1982-04-26

1983-03-08

Gantz, Delbert E.

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

Polycyclic product

585477, C07C 524, C07C 530

Patent

active

043762247

ABSTRACT:
A method is disclosed for promoting isomerization of sym-octahydrophenanthrene (s-OHP) to sym-octahydroanthracene (s-OHA) in the presence of a catalyst provided by aluminum chloride or aluminum bromide, or a mixture of these two compounds. The rate of isomerization is increased by having the reaction run in the presence of an acyl peroxide such as benzoyl peroxide or lauroyl peroxide.

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