Alternating block copolymers of polyarylene polyethers and proce

Details Alternating block copolymers of polyarylene polyethers and proce Alternating block copolymers of polyarylene polyethers and proce

1984-09-28

1987-01-20

Phynes, Lucille M.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

525535, C08F28300, C08G 7500

Patent

active

046380396

ABSTRACT:
A modified Williamson etherification in the presence of phase transfer catalyst is used to synthesize alternating block copolymers and regular copolymers. Unsaturated polyethers of a polynuclear dihydric phenol containing chloroallylic (electrophilic) end groups (prepared from cis- or trans-1,4-dichloro-2-butene and Bisphenol A) and aromatic poly(ether sulfone)s containing terminal phenol (nucleophilic) groups are polycondensed in the presence of tetrabutylammonium hydrogen sulfate as phase transfer catalyst to give alternating block copolymers. The same telechelic polymers were chain-extended with dinucleophilic or dielectrophilic monomers under similar reaction conditions. Both the regular copolymers and the alternating block copolymers were characterized by gel permeation chromatography and DSC.

REFERENCES:
patent: 3717618 (1973-02-01), Oswald
patent: 4116936 (1978-09-01), Stelner
patent: 4258175 (1981-03-01), Chen
patent: 4431761 (1984-02-01), Hergenrother
patent: 4471106 (1984-09-01), Luecke et al.
patent: 4486576 (1984-12-01), Colon et al.
patent: 4510296 (1985-04-01), Hergenrother
patent: 4562243 (1985-12-01), Percec

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