Alternating (ABA)N polylactide block copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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525415, 528 26, 528 28, 528 76, 528 83, 528300, 528301, 528341, C08G 6308

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active

052024130

ABSTRACT:
Polymers of the general formula R--(A-B-A-I)-.sub.x A-B-A-R and their preparation are disclosed. In the general formula, -A- is a polyhydroxy acid residue preferably a polymer of either 98 to 100% L-lactide or 98 to 100% D-lactide having a molecular weight of 500 to 40,000 and preferably 2,000 to 20,000, -B- is an oligomeric diol or diamine residue, having a number average molecular weight of 500 to 20,000 and preferably 2,000 to 8,000. The polymers are prepared by polymerizing a lactone onto the diol or diamine followed by reacting the resulting polymeric H-A-B-A-H with an diisocyanate or diacyl chloride to form the -L- chain extending units in the general formula.

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