Alpha-olefin polymerization catalyst and process

Details Alpha-olefin polymerization catalyst and process Alpha-olefin polymerization catalyst and process

1979-07-03

1981-03-10

Garvin, Patrick

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

526136, 526141, 526142, C08F 464

Patent

active

042552818

ABSTRACT:
Process for modifying a titanium trichloride-organoaluminum alpha-olefin polymerization catalyst to reduce production of alkane soluble products during polymerization of alpha-olefins in the presence of such catalyst without substantial decreases in catalyst activity, said process comprising combining in an inert diluent and in the substantial absence of catalyst poisons, components comprising an alkylaluminum component, a titanium trichloride, hydrogen sulfide or a bis-(trialkyltin)sulfide, a tertiary amine, and an aromatic dicarbonyl compound selected from the group consisting of dialdehydes and lower alkyl diesters of ortho-, para- and meta-phthalic acids. Polyalpha-olefins containing reduced levels of low molecular weight and amorphous components are produced by contacting the catalysts with at least one polymerizable alpha-olefin under polymerizing conditions.

REFERENCES:
patent: 3129256 (1964-04-01), Hay et al.
patent: 3367923 (1968-02-01), Tanaka et al.
patent: 3496158 (1970-02-01), Fisher et al.
patent: 3549717 (1970-12-01), Itakura et al.
patent: 3670043 (1972-06-01), Kubicek et al.
patent: 3950268 (1976-04-01), Karayannis et al.
patent: 3984350 (1976-10-01), Karayannis et al.
patent: 4072809 (1978-02-01), Rogan

Affiliated with

Also associated with

Rating

Alpha-olefin polymerization catalyst and process does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Alpha-olefin polymerization catalyst and process, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Alpha-olefin polymerization catalyst and process will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1293195