Alpha-olefin oligomerization using supported metal halide cataly

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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502113, 502152, 502231, 585521, 585532, 585533, C07C 230

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054517044

ABSTRACT:
A process for the production of hydrocarbon lubricant basestock comprises contacting C.sub.2 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, e.g., 1-decene, under heterogeneous oligomerization conditions with a catalyst comprising halides of a metal component anchored on an adsorbent inorganic oxide solid, e.g., silica, by an oxygen-metal bond to provide a reaction mixture containing said hydrocarbon lubricant basestock. The catalyst is prepared by contacting the inorganic oxide solid with organic metal halide of the formula RMXY wherein R is alkyl or aryl, M is aluminum, X is halogen and Y is selected from the group consisting of halogen, alkyl, alkenyl, aryl, alkoxy, and amido moieties.

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