.alpha.-Olefin dimer isomerization using organo-halogens

Details .alpha.-Olefin dimer isomerization using organo-halogens .alpha.-Olefin dimer isomerization using organo-halogens

1978-07-28

1980-06-24

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Plural serial diverse syntheses

Same catalyst, solvent, or component thereof used in both...

C07C 524, C07C 321

Patent

active

042096537

ABSTRACT:
A process for isomerization of .alpha.-olefin dimers which comprises dimerizing a lower .alpha.-olefin with a Ziegler type catalyst comprising a nickel compound and an organo-aluminum compound, and then continuing the reaction with addition of at least one compound, prior to deactivation of said catalyst, which is selected from the group consisting of the following organo-halogen compounds of the formulae (I), (II), (III) and (IV), ##STR1## wherein X.sup.1 to X.sup.11 are the same or different and are each a halogen or hydrogen atom or an alkyl group having 1 to 20 carbon atoms and at least one of them in each formula is a halogen atom, R is a hydrocarbon group having 1 to 20 carbon atoms, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are each a hydrogen or halogen atom or a hydrocarbon group having 1 to 20 carbon atoms, R.sup.4 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, R.sup.5 and R.sup.6 are the same or different and are each an alkyl having 1 to 20 carbon atoms or, taken together, may form a cycloalkyl group, and n is an integer of 0 to 5.

REFERENCES:
patent: 3454668 (1969-07-01), Down et al.
patent: 3542896 (1970-11-01), Butte
patent: 3644558 (1972-02-01), Wilke et al.
patent: 3686352 (1972-08-01), Neal
patent: 3709953 (1973-01-01), Bergene et al.
patent: 3903188 (1975-09-01), Citron
patent: 4155946 (1979-05-01), Sato et al.

Affiliated with

Also associated with

Rating

.alpha.-Olefin dimer isomerization using organo-halogens does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with .alpha.-Olefin dimer isomerization using organo-halogens, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and .alpha.-Olefin dimer isomerization using organo-halogens will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1481639