Alpha-olefin conversion

Details Alpha-olefin conversion Alpha-olefin conversion

1983-04-21

1985-03-26

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

252470, 502103, C07C 4534

Patent

active

045075069

ABSTRACT:
The conversion of long-chain alpha-olefins to methyl ketones can be efficiently carried out using reaction systems containing palladium, a co-catalyst, and an aqueous solvent system.

REFERENCES:
patent: 3255238 (1966-06-01), Roelen et al.
patent: 3365498 (1968-01-01), Bryant
patent: 3485877 (1969-12-01), Hargis et al.
patent: 4085145 (1978-04-01), Mimoun et al.
patent: 4152354 (1979-05-01), Stapp
patent: 4237331 (1980-12-01), Stapp
patent: 4271320 (1981-06-01), Takitoh et al.
Lloyd et al., J. Org. Chem., vol. 34, pp. 3949-3951, (1969).
Clement et al., "Improved Procedures for Converting Higher .alpha.-Olefins to Methyl Ketones with Palladium Chloride", Journal of Organic Chemistry, vol. 29, pp. 241-243, (1974).
Fahey et al., "Aqueous Sulfolane as Solvent for Rapid Oxidation of Higher .alpha.-Olefins to Ketones Using Palladium Chloride", Journal of Organic Chemistry, vol. 39, No. 22, pp. 3276-3277, (1974).

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