Alpha halo substituted asymmetrical diacyl peroxides in co-initi

Details Alpha halo substituted asymmetrical diacyl peroxides in co-initi Alpha halo substituted asymmetrical diacyl peroxides in co-initi

1977-03-04

1978-08-15

Lilling, Herbert J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526223, 526330, 526344, 526345, C08F 438, C08F 1406, C08F21406

Patent

active

041074190

ABSTRACT:
Organic peroxide polymerization co-initiator compositions and their use in the initiation of the polymerization of certain monomers and comonomers such as vinyl chloride, ethylene and methyl methacrylate. The co-initiator composition contains an alpha halo substituted diacyl peroxide and a coperoxide selected from t-alkyl peresters of t-hydroperoxides, peroxydicarbonates, acyl peroxycarbonic esters, and aliphatic diacyl peroxides. Typical is acetyl 2-chlorooctanoyl peroxide with t-butyl peroxy neodecanoate.

REFERENCES:
patent: RE25763 (1965-04-01), Marous et al.
patent: 3420807 (1969-01-01), Harrison et al.
patent: 3558537 (1971-01-01), Hecker et al.
patent: 3652524 (1972-03-01), Lewis et al.
patent: 3652681 (1972-03-01), Wood
patent: 3714135 (1973-01-01), Pfannmueller et al.
patent: 3763128 (1973-10-01), Lewis et al.
patent: 3781255 (1973-12-01), Balwe et al.
patent: 3817965 (1974-06-01), Mace et al.
patent: 3932372 (1976-01-01), Lewis et al.

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