Alpha halo substituted asymmetrical diacyl peroxides in co-initi

Details Alpha halo substituted asymmetrical diacyl peroxides in co-initi Alpha halo substituted asymmetrical diacyl peroxides in co-initi

1976-11-08

1978-07-25

Gantz, Delbert E.

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

526228, 526231, B01J 3102

Patent

active

041028155

ABSTRACT:
Organic peroxide polymerization co-initiator compositions and their use in the initiation of the polymerization of certain monomers and comonomers such as vinyl chloride, ethylene and methyl methacrylate. The co-initiator composition contains an alpha halo substituted diacyl peroxide and a coperoxide selected from t-alkyl peresters of t-hydroperoxides, peroxydicarbonates, acyl peroxycarbonic esters, and aliphatic diacyl peroxides. Typical is acetyl 2-chlorooctanoyl peroxide with t-butyl peroxy neodecanoate.

REFERENCES:
patent: 3420807 (1969-01-01), Harrison et al.
patent: 3639370 (1972-02-01), Edl et al.
patent: 3652524 (1972-03-01), Lewis et al.
patent: 3652681 (1972-03-01), Wood
patent: 3687867 (1972-08-01), Lewis et al.
patent: 3736306 (1973-05-01), Light
patent: 3763128 (1973-10-01), Lewis et al.
patent: 3778422 (1973-12-01), Farber et al.
patent: 3781255 (1973-12-01), Balwe et al.

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