Alpha-ethynyl benzohydrols

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2605707, 260618H, 260611A, 260574, 260558P, 424330, 424345, 424340, 424341, 260618E, C07C 3304

Patent

active

039651797

ABSTRACT:
The invention is a new process for the preparation of .alpha.-ethynyl-benzohydrols and of ring-substituted derivatives thereof by reacting the starting benzophenone or a ring-substituted derivative thereof with acetylene in a solvent delivering no protons, in the presence of an alkali metal tertiary alcoholate, preferably potassium-tert.-butylate or potassium-tert.-amylate. Also new substituted derivatives of .alpha.-ethynyl-benzhydrol are prepared by the invention.

REFERENCES:
patent: 2996552 (1961-07-01), Blumenthal
patent: 3560567 (1971-02-01), Ruegg et al.
patent: 3663628 (1972-05-01), Tedeschi
patent: 3759906 (1973-09-01), Cavalla et al.
Gould et al., J.A.C.S., vol. 57, pp. 340-345 (1935).
Chadkiewicz et al., Compt rend. vol. 250, pp. 150-152 (1960).
March et al., J. Enco. Entomol., vol. 45, pp. 851-853, (1952).

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