Metal treatment – Process of modifying or maintaining internal physical... – Heating or cooling of solid metal
Reexamination Certificate
1999-03-31
2002-11-05
Andrews, Melvyn (Department: 1742)
Metal treatment
Process of modifying or maintaining internal physical...
Heating or cooling of solid metal
C148S676000, C148S668000
Reexamination Certificate
active
06475311
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to alloys that can be used as substrates for superconductors, to superconductors including such substrates, and to methods of making these alloys and superconductors.
Superconductors, including oxide superconductors, are used in a variety of applications. Some superconductors can demonstrate limited mechanical strength. Often, the mechanical strength of a superconductor can be enhanced by forming a multilayer article that includes a layer of superconductor material and a substrate layer, but the substrate should exhibit certain properties.
The substrate should have a low Curie temperature so that the substrate is not ferromagnetic below the superconductor's critical temperature. Furthermore, chemical species within the substrate should not be able to diffuse into the layer of superconductor material, and the coefficient of thermal expansion of the substrate should be about the same as or somewhat higher than the superconductor material. Moreover, if the substrate is used for an oxide superconductor, the substrate material should be relatively resistant to oxidation.
For some materials, such as YBa
2
Cu
3
O
x
(YBCO), the ability of the material to act as a superconductor depends upon the crystallographic orientation of the material. For these superconductors, the substrate should have a crystallographic orientation that allows the material to act as a superconductor. Often, good superconducting properties are observed in these materials when the substrate has a biaxially textured surface. One type of biaxial texture is cube texture, in which the lattice is oriented such that the cube texture, in which the lattice is oriented such that the cube face is parallel to the surface. In addition, the cube edge in each crystallite is parallel to the cube edge in all neighboring crystallites. Examples of cube textured surfaces include the (
100
)[
001
] and (
100
)[
011
] surfaces, and an example of a biaxially textured surface is the (
113
)[
211
] surface.
Some substrates do not readily meet all these requirements, so one or more buffer layers can be disposed between the substrate and the superconductor layer. The buffer layer(s) can be comparatively resistant to oxidation, and reduce the diffusion of chemical species between the substrate and the superconductor layer. Moreover, the buffer layer(s) can have a coefficient of thermal expansion and a crystallographic orientation that is well matched with the superconductor material.
Buffer layers are commonly formed using epitaxy. An epitaxial layer is a layer of material that is grown on a surface such that the crystallographic orientation of the layer of material is determined by the lattice structure of the surface on which the layer is grown. For example, for an epitaxial buffer layer grown on the surface of a substrate layer, the crystallographic orientation of the epitaxial layer is determined by the lattice structure of the surface of the substrate layer. Techniques used to grow epitaxial buffer layers include chemical vapor deposition and physical vapor deposition.
Some pure metals, such as copper and nickel, can be prepared to have a desirable crystallographic orientation (e.g, a biaxial texture or cube texture) by a process that involves first rolling the metal and then annealing the metal. However, these pure metals may exhibit certain properties that are inappropriate for a substrate. For
Attempts have been made to provide substrates for superconductors that are crystallographically oriented alloys. These substrates have been formed by first rolling and annealing a metal, then diffusing a different metal into the pure metal to form the alloy. This can result in a nonhomogeneous alloy.
SUMMARY OF THE INVENTION
The invention relates to alloys that can be used as substrates for superconductors, to superconductors including such substrates, and to methods of making these alloys and superconductors. The alloys can exhibit a variety of advantages, including good oxidation resistance, low Curie temperature, good homogeneity, and/or good surface texture.
In one aspect, the invention features a substantially homogeneous alloy including nickel and chromium. The alloy has a cube texture surface. At least about 65 volume percent of the alloy has a cube texture. The alloy can be made by a process that includes rolling the alloy, and then annealing the alloy.
In another aspect, the invention features an article that includes a substrate and a layer. The substrate is formed of a substantially homogeneous alloy including nickel and chromium. The alloy has a cube texture surface, and the layer is supported by the cube texture surface. The alloy can be made by a process that includes rolling the alloy, and then annealing the alloy.
The alloys preferably have a Curie temperature of less than about 80 K (e.g., less than about 40 K or less than about 20 K).
The alloys can be homogeneous alloys.
The alloys can be relatively resistant to oxidation.
The alloys can have a surface that is biaxially textured or cube textured.
A relatively large volume percent of the alloys can be cube textured.
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Fritzemeier Leslie G.
Hans Thieme Cornelis Leo
Thompson Elliott D.
American Superconductor Corporation
Andrews Melvyn
Fish & Richardson P.C.
Wilkins, III Harry D.
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