Alkylation with separate butene streams including isobutylene

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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26068349, C07C 354

Patent

active

039989038

ABSTRACT:
A process for producing an alkylation reaction product from an isoparaffin and an olefinic reactant containing 1-butene, 2-butene and isobutylene by fractionating the olefinic reactant into a 2-butene fraction and a separate 1-butene and isobutylene fraction. The 2-butene is charged to an HF alkylation reaction zone with isobutane. The mixture is heated by the endothermic reaction, and the fraction comprising 1-butene and isobutylene is then added to the unitary reaction zone. It is possible to alkylate these olefins at conditions which are close to the optimum conditions, using a single reactor vessel, which operates at different temperatures without the necessity for heat exchange means.

REFERENCES:
patent: 2322800 (1943-06-01), Frey
patent: 2467731 (1949-04-01), Dart et al.
patent: 3560587 (1971-02-01), Borst, Jr.
patent: 3778489 (1973-12-01), Parker et al.
patent: 3810955 (1974-05-01), Sobel

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