Alkylation of vinylidene chloride and vinylidene bromide

Details Alkylation of vinylidene chloride and vinylidene bromide Alkylation of vinylidene chloride and vinylidene bromide

1974-08-08

1976-05-11

Horwitz, D.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260654R, C07C 1726, C07C 2104, C07C 2102, C07C 2518

Patent

active

039564118

ABSTRACT:
Vinylidene chloride and vinylidene bromide are alkylated by reaction with alkylating agents such as selected olefins, tert-alkyl halides, and secondary or tertiary alcohols in a reaction medium comprising trifluoromethane-sulfonic acid. In specific embodiments, the reaction medium can additionally comprise water, methanol, and BF.sub.3.

REFERENCES:
patent: 2481159 (1949-09-01), Schmerling
patent: 3708553 (1973-01-01), Olah
patent: 3778489 (1973-12-01), Parker et al.

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