Alkylation of polyamines

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...

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544358, 544402, 546184, 546194, 546246, 564305, 564306, 564307, 564309, 564336, 564340, 564343, 564346, 564355, 564374, 564378, 564389, 564391, 564395, 564396, 564399, 564401, 564408, 564445, 564467, C07D24104, C07D29500, C07D21100, C07C 8518

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043225306

ABSTRACT:
A process for alkylating a polyamine by contacting, in a liquid media, a polyamine, an olefinic compound, carbon monoxide, and a hydrogen source in the presence of a catalytic amount of a rhodium atom containing compound selected from metallic rhodium, rhodium salts, rhodium oxides, rhodium carbonyls and ligands thereof at a temperature of from about 50.degree. C. to 250.degree. C. and at a pressure of from about 30 to about 300 atmospheres.

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Houben-Weyl, "Methoden der Organischen Chemie", 4th Ed., vol. 11/1, pp. 994-999, (1957).

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