Alkylation of aromatics using a fluorided silica-alumina catalys

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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585455, 585456, 585462, 585463, 585467, 585468, 252553, 252556, 252558, 568631, 568632, 568658, 568731, 568732, 568734, 568736, 568766, 568780, 568781, 568785, 568790, 568804, 562 79, 562 82, 562 88, 562 91, 562 94, 562 95, 562 99, C07C 3912, C07C 3700, C07C 264, C07C 15107, C07C 4100, C07C 266, C07C 270, C07C 268

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053449975

ABSTRACT:
A fluorided silica-alumina catalyst, particularly one with a silica:alumina ratio in the range of 1:1-9:1 containing from 1 to 6 weight percent fluoride, is particularly effective in the liquid phase alkylation of benzene by linear olefins to produce linear alkyl benzenes at temperatures no greater than 140.degree. C. These catalysts also are effective in the liquid phase alkylation of alkylatable aromatics generally with a variety of alkylating agents, including olefins, alcohols, and alkyl halides.

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Kurosaki and Okazaki, Bull. Chem. Soc., Japan, 63,2363 (1990).
Kurosaki and Okazaki, Chemistry Letters, 589 (1991).
R. A. Myers, "Petroleum Refining Processes", 4-36 to 4-38 (McGraw-Hill Book Company), 1986.

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