Alkylation of aromatic compounds with silicalite catalysts in th

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585323, 252449, 252455Z, C07C 352

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043872603

ABSTRACT:
A process and apparatus for alkylating aromatic compounds with silicalite alkylation catalysts in the presence of an effective amount of water which extends the cycle length of the reaction by decreasing the rate of activity loss of the catalyst and decreases the production of unwanted by-products.

REFERENCES:
patent: 4016218 (1977-04-01), Haag et al.
patent: 4016218 (1977-04-01), Haag et al.
patent: 4283306 (1981-08-01), Herkes
patent: 4283306 (1981-08-01), Herkes
Flanigan et al., Nature 271, 512 (1978).
Olsen et al., J. Catalysis, 61, 390 (1980).
Bibby et al., Nature, 280, 664 (1979).
"Silicalite, A New Hydrophobic Crystalline Silica Molecular Sieve" Flanigan et al., Nature 271, 512 (1978).
"Chemical and Physical Properties of ZSM-5 Substitutional Series", Olsen et al., Jo. of Catalipir, 61, 390 (1980).
"Siliclite-2, A Silica Analogne of the Alumino-Silicate Zeolite ZSM-11", Bibby et al., Nature, 280, 664 (1979).

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