Alkylation of aromatic compounds

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585449, 585452, 585475, 568791, 568794, 564409, C07C 266, C07C 3748, C07C20968

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active

051985950

ABSTRACT:
Monoalkylated benzene such as ethylbenzene and cumene or monoalkylated substituted benzene are produced by alkylation in the presence of an acidic mordenite zeolite catalyst having a silica/alumina molar ratio of at least 40:1, preferably 160:1. In a subsequent, optional process, the polyalkylated benzene or polyalkylated substituted benzene produced in the alkylation is transalkylated in the presence of an acidic mordenite zeolite catalyst.

REFERENCES:
patent: 2431166 (1943-04-01), Buell et al.
patent: 3140253 (1964-05-01), Plank et al.
patent: 3251897 (1966-05-01), Wise
patent: 3367884 (1968-02-01), Reid et al.
patent: 3480539 (1968-10-01), Voorhies et al.
patent: 3485748 (1968-12-01), Eberly et al.
patent: 3551510 (1968-08-01), Pollitzer et al.
patent: 3562345 (1971-02-01), Mitsche
patent: 3597155 (1971-08-01), Flannigan et al.
patent: 3597493 (1971-08-01), Frilette et al.
patent: 3631120 (1971-12-01), Eberly et al.
patent: 3641177 (1972-02-01), Eberly et al.
patent: 3699181 (1972-10-01), Kamecak et al.
patent: 3716597 (1973-02-01), Mitsche et al.
patent: 3719026 (1973-03-01), Sand
patent: 3758667 (1973-09-01), Kouwenhoven et al.
patent: 3763260 (1973-10-01), Pollitzer
patent: 3849340 (1974-11-01), Pollitzer
patent: 3873632 (1975-03-01), Pollitzer
patent: 3972832 (1976-08-01), Butter et al.
patent: 4085156 (1978-04-01), Filette et al.
patent: 4108908 (1978-08-01), Rutledge
patent: 4151120 (1979-08-01), Marcilly
patent: 4169111 (1979-09-01), Wight
patent: 4180693 (1979-12-01), Marcilly
patent: 4182692 (1980-01-01), Kovosky et al.
patent: 4185040 (1980-01-01), Ward et al.
patent: 4240932 (1980-12-01), Alafandi et al.
patent: 4263466 (1981-04-01), Colon et al.
patent: 4283573 (1981-08-01), Young
patent: 4301317 (1981-11-01), Young
patent: 4323481 (1982-04-01), Kaduk
patent: 4361713 (1982-11-01), Kaeding
patent: 4371714 (1983-02-01), Young
patent: 4376104 (1983-03-01), Ball et al.
patent: 4420418 (1983-12-01), Chu
patent: 4447669 (1984-05-01), Hamon et al.
patent: 4459426 (1984-07-01), Inwood et al.
patent: 4480142 (1984-10-01), Cobb
patent: 4501656 (1985-02-01), Dufresne et al.
patent: 4525466 (1985-06-01), Moretti et al.
patent: 4665258 (1987-05-01), Butler et al.
patent: 4731497 (1988-03-01), Grey
patent: 4745095 (1988-05-01), Saito et al.
patent: 4774377 (1988-09-01), Barger et al.
patent: 4849570 (1989-07-01), Bakas et al.
patent: 4857666 (1989-08-01), Barger et al.
Studies in Surface Science and Catalysis, V18, (1984), pp. 133-140; H. K. Beyer et al. Structural Peculiarities and Stabilsation phenomena of Aluminum Deficient Mordenites.
Zeolites, V7, (1987), pp. 427-433, M. Musa, et al.; Some structural characteristics of dealuminated sythetic mordenites.
Derwent, 84-141746/23JP, (1982).
Derwent; 78145 D/43 FR, (1980).
Derwent; 76464A/43 FARF, (1976).
Derwent, 86-065632/10JP, (1981).
Polish Journal of Chem., 60,255.(1986); B. Sulikowski et al. Effect of Dealumination on Sorption Properties of Zeolon 300, 900 and 500.
Bulletin of the Acad. of Sciences of USSR, #7, 1971, pp. 1298-1303, I. M. Belen'kaya et al.; Formation and Properties of the Hydrogen Form of Mordenite.
Bulletin of the Acad. of Sciences of USSR, #12, 1971, pp. 2505-2509, I. M. Belen'kaya et al. Formation and Properties of the Hydrogen Form of Mordenite.
Journal of Catalysis, 28 (1973), pp. 403-413, K. A. Becker et al.; Benzene Alkylation with Ethylene and Propylene over H-Mordenite as Catalyst.
Kinetika i Kalatiz, V19, No. 1, pp. 256-259, (1978), M. I. Dashevskii, et al.; Electron Microscopic Study of a Nickel-Mordenite Catalyst.
Kirk-Othmer Encyclopedia of Chemical Technology, 3rd Ed., vol. 14, John Wiley & Sons N.Y., N.Y., pp. 395-427.
D. W. Breck, Zeolite Molecular Sieves, John Wiley & Sons, (1974) pp. 122-124 and 162-163.
J. D. Sherman and J. M. Bennett, "Framework Structures Related to the Zeolite Mordenite," Molecular Sieves, Advances in Chemistry Series, 121 (1973), pp. 52-65.
Chemical Abstracts 82:169681b (1975).
Chemical Abstracts 82:57148b (1975).

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