Alkylation of aromatic amines over Al exchanged zeolites

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C 8524

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active

048515795

ABSTRACT:
This present invention is a process for alkylating aromatic amines to form ortho-alkylated products in high selectivity relative to N-alkylated products. Aromatic amines are contacted with an olefin or an alcohol in the presence of an ion exchanged zeolite in which at least a portion of the exchangeable ion sites have been exchanged with Al cations.

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