Alkylated phosphazene oligomers and polymers and method of prepa

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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260543P, 528397, 528399, 568 12, C08G 7300

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active

042581729

ABSTRACT:
Alkylated phosphazene oligomers of the general formula (NP(X.sub.2)).sub.n PRH, wherein X represents chlorine or bromine, R represents a linear or branched alkyl, and n represents an integer from 2 to 8, are prepared by reacting, in a nonoxidizing atmosphere, a perhalopolyphosphazene, a Grignard reagent, and a cuprous complex in solution, followed by the addition of a secondary or tertiary alcohol. Polymers useful as high-temperature elastomers, are prepared from the halo-substituted oligomers by heating them at a temperature from about 200.degree. C. to about 300.degree. C., followed by a reaction with an amine, metal alkoxide, or a metal aryloxide at a temperature from 20.degree. to 200.degree. C.

REFERENCES:
patent: 3453235 (1969-07-01), Klender
patent: 4136084 (1979-01-01), Dieck et al.

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