Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate
Patent
1979-09-25
1981-03-24
Briggs, Sr., Wilbert J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From phenol, phenol ether, or inorganic phenolate
260543P, 528397, 528399, 568 12, C08G 7300
Patent
active
042581729
ABSTRACT:
Alkylated phosphazene oligomers of the general formula (NP(X.sub.2)).sub.n PRH, wherein X represents chlorine or bromine, R represents a linear or branched alkyl, and n represents an integer from 2 to 8, are prepared by reacting, in a nonoxidizing atmosphere, a perhalopolyphosphazene, a Grignard reagent, and a cuprous complex in solution, followed by the addition of a secondary or tertiary alcohol. Polymers useful as high-temperature elastomers, are prepared from the halo-substituted oligomers by heating them at a temperature from about 200.degree. C. to about 300.degree. C., followed by a reaction with an amine, metal alkoxide, or a metal aryloxide at a temperature from 20.degree. to 200.degree. C.
REFERENCES:
patent: 3453235 (1969-07-01), Klender
patent: 4136084 (1979-01-01), Dieck et al.
Allcock Harry R.
Harris Paul J.
Briggs Sr. Wilbert J.
Ellis William T.
Sciascia R. S.
The United States of America as represented by the Secretary of
Zirker Daniel R.
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