Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives
Patent
1988-02-26
1989-08-29
Griffin, Ronald W.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carbohydrates or derivatives
106162, 1061631, 106210, 106205, 106208, 210656, 536 20, 536 30, 536 45, 536 51, C08B 1506, C08B 3300, C08B 3702, C08B 3708
Patent
active
048618721
ABSTRACT:
An alkyl-phenylcarbamate derivative of a polysaccharide has in 80 to 100 percent of hydrogen atoms of the amino and hydroxyl groups an alkylphenyl-carbamoyl group having the formula (I): ##STR1## in which (1) at least one of R1 to R5 is a straight alkyl having 4 to 8 or a branched alkyl having 3 to 8 carbon atoms or at least two of R1 to R5 each are a straight alkyl having 1 to 3 when the polysaccharide is cellulose; (2) at least one of R1 to R5 is a straight alkyl having 1 to 8 carbon atoms or a branched alkyl having 3 to 8 carbon atoms when the polysaccharide is any one other than cellulose; and the other(s) of R1 to R5 is hydrogen. It is useful to optical separation of a racemic mixture.
REFERENCES:
McCormick et al., "Homogeneous Solution Reactions of Cellulose, Chitin, and Other Polysaccharides", 1980 American Chemical Society, pp. 372-380.
Yoshio Okamoto et al, "Controlled Chiral Recognition of Cellulose Triphenylcarbamate Derivatives Supported on Silica Gel", 1986 Journal of Chromatography, pp. 173-186.
Hatada Koichi
Okamoto Yoshio
Daicel Chemical Industries Ltd.
Griffin Ronald W.
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