Alkyl ethers of Binor-S

Details Alkyl ethers of Binor-S Alkyl ethers of Binor-S

1975-05-16

1977-12-20

Helfin, Bernard

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

44 78, 149120, 1491094, C07C 4318

Patent

active

040641805

ABSTRACT:
Ionic alcoholysis of Binor-S, a C.sub.14 heptacyclic, saturated hydrocarbon, in the presence of a primary alcohol and hydrogen, yields a low melting point product containing novel alkyl ethers of Binor-S. Alcoholysis occurs at about 50.degree.-300.degree. C. and at about 100-10,000 p.s.i.g. in the presence of Raney nickel, palladium-on-carbon or palladium-on-alumina catalyst promoted by a hydrogen halide or its equivalent. Resulting product has utility as a high energy fuel.

REFERENCES:
paquette et al., J.A.C.S. 94, (1972), pp. 5096-5098.
Monick, Alcohols, (1968), 93, 94, 150-152.

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