Alkyl 3-oxoalkanoate and process for the preparation thereof

Details Alkyl 3-oxoalkanoate and process for the preparation thereof Alkyl 3-oxoalkanoate and process for the preparation thereof

1996-10-15

2000-07-18

Barts, Samuel

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560174, 560177, 560 51, 560 53, 560217, 560219, 560168, 562553, 568811, C07C 6966, C07C 6962, C07C 3326

Patent

active

060909749

ABSTRACT:
This invention includes an alkyl 3-oxoalkanoate, and processes for its preparation and use for the synthesis of fatty hydroxylated amino acids, fatty amino alcohols and ceramides.

REFERENCES:
patent: 4206120 (1980-06-01), Hunt
M. Viscontini, "Reduction des substances Beta-amino-alpha, gamma-dicarbonylees; une nouvelle synthese de l'allo-DL-phenyl-3-amino-2-propane-diol-1,3 (DL-erythro-phenylserinol)," Helvetica Chimica Acta, vol. XXXV, Oct. 1952, pp. 1803-1805.
March, "Reduction of Nitroso Compounds and Hydroxylamines to Amines," Advanced Organic Chemistry, 1985, John Wiley & Sons, 3d Ed., p. 1105.
Houben-Weyl, "Reduktion von Oximen (Isonitros overbindungen) und Hyroxylaminen," Methoden der Organischen Chemie, vol. XI/1, 1957, pp. 495-506.
Sisido et al., "Synthesis of Racemic Phytophingosine and the lyxo Isomer," Journal of Organic Chemistry, vol. 34, No. 11, Nov. 1969, pp. 3539-3544.
Chemical Abstracts, vol. 98, No. 1, Jan. 3, 1983, "Reactions of Esters of Alpha-(Bromoacyl)Acetic Acid with Sodium Thioacetate," p. 4452, Column R, Abstract No. 4551u.
Journal of the Chemical Society, Perking Transactions 1, No. 2, Feb. 1987, pp. 333-343, Leslie Crombie et al., "Synthesis of the Mammea Coumarins, Part 2, Experiments in the Mammea E Series and Synthesis of Mammea E/AC".
Journal of Organic Chemistry, vol. 43, No. 10, May 12, 1978, pp. 2087-2088, Yuji Oikawa et al., "Meldrum's Acid in Organic Chemistry 2: A General and Versatile of Beta-Keto Esters".
Ansari et al., Peracid oxidation . . . fatty acids, Chem. Phys. Lipids, 29(1), pp. 45-53, 1981.
G. Gregory et al., "Synthesis of Racemic 2-Amino-octadecane-I: 3-diols," Journal of the Chemical Society, Part III., pp. 2453-2456 (1951).

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